Nonlinear Optical Properties and Temperature-Dependent UV-Vis Absorption and Photoluminescence Emission in 2D Hexagonal Boron Nitride Nanosheets

Pathik Kumbhakar, Arup Kanti Kole, Chandra Sekhar Tiwary, Subrata Biswas, Soumya Vinod, Jaime Taha-Tijerina, Udit Chatterjee, Pulickel M. Ajayan

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© 2015 WILEY-VCH Verlag GmbH & Co. Recently, a lot of interest has been centred on the optical properties of hexagonal boron nitride (h-BN), which has a similar lattice structure to graphene. Interestingly, h-BN has a wide bandgap and is biocompatible, so it has potential applications in multiphoton bioimaging, if it can exhibit large nonlinear optical (NLO) properties. However, extensive investigation into the NLO properties of h-BN have not been done so far. Here, NLO properties of 2D h-BN nanosheets (BNNS) are reported for the first time, using 1064-nm NIR laser radiation with a pulse duration of 10 ns using the Z-scan technique. The reverse saturable absorption occurs in aqueous colloidal solutions of BNNS with a very large two-photon absorption cross section (σ2PA) of ≈57 × 10-46cm4s-1photon-1. Also, by using UV-Vis absorption spectroscopy, the temperature coefficient of the bandgap (dEg/dT) of BNNS is determined to be 5.9 meV K-1. Further defect-induced photoluminescence emission in the UV region is obtained in the 283-303 K temperature range, under excitations of different wavelengths. The present report of large σ2PAcombined with stability and biocompatibility could open up new possibilities for the application of BNNS as a potential optical material for multiphoton bioimaging and advanced photonic devices.
Original languageEnglish
Pages (from-to)828-835
Number of pages8
JournalAdvanced Optical Materials
Publication statusPublished - 1 Jun 2015
Externally publishedYes


All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

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