Electrically insulating thermal nano-oils using 2D fillers

Jaime Taha-Tijerina, Tharangattu N. Narayanan, Guanhui Gao, Matthew Rohde, Dmitri A. Tsentalovich, Matteo Pasquali, Pulickel M. Ajayan

Research output: Contribution to journalArticle

126 Citations (Scopus)

Abstract

Different nanoscale fillers have been used to create composite fluids for applications such as thermal management. The ever increasing thermal loads in applications now require advanced operational fluids, for example, high thermal conductivity dielectric oils in transformers. These oils require excellent filler dispersion, high thermal conduction, but also electrical insulation. Such thermal oils that conform to this thermal/electrical requirement, and yet remain in highly suspended stable state, have not yet been synthesized. We report here the synthesis and characterization of stable high thermal conductivity Newtonian nanofluids using exfoliated layers of hexagonal boron nitride in oil without compromising its electrically insulating property. Two-dimensional nanosheets of hexagonal boron nitride are liquid exfoliated in isopropyl alcohol and redispersed in mineral oil, used as standard transformer oil, forming stable nanosuspensions with high shelf life. A high electrical resistivity, even higher than that of the base oil, is maintained for the nano-oil containing small weight fraction of the filler (0.01 wt %), whereas the thermal conductivity was enhanced. The low dissipation factor and high pour point for this nano-oil suggests several applications in thermal management. © 2012 American Chemical Society.
Original languageEnglish
Pages (from-to)1214-1220
Number of pages7
JournalACS Nano
DOIs
Publication statusPublished - 28 Feb 2012
Externally publishedYes

Fingerprint

fillers
Fillers
Oils
oils
Thermal conductivity
Boron nitride
thermal conductivity
Temperature control
boron nitrides
transformers
Mineral Oil
Insulating oil
Fluids
2-Propanol
electrical insulation
Nanosheets
Mineral oils
mineral oils
isopropyl alcohol
Thermal load

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Taha-Tijerina, J., Narayanan, T. N., Gao, G., Rohde, M., Tsentalovich, D. A., Pasquali, M., & Ajayan, P. M. (2012). Electrically insulating thermal nano-oils using 2D fillers. ACS Nano, 1214-1220. https://doi.org/10.1021/nn203862p
Taha-Tijerina, Jaime ; Narayanan, Tharangattu N. ; Gao, Guanhui ; Rohde, Matthew ; Tsentalovich, Dmitri A. ; Pasquali, Matteo ; Ajayan, Pulickel M. / Electrically insulating thermal nano-oils using 2D fillers. In: ACS Nano. 2012 ; pp. 1214-1220.
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Taha-Tijerina, J, Narayanan, TN, Gao, G, Rohde, M, Tsentalovich, DA, Pasquali, M & Ajayan, PM 2012, 'Electrically insulating thermal nano-oils using 2D fillers', ACS Nano, pp. 1214-1220. https://doi.org/10.1021/nn203862p

Electrically insulating thermal nano-oils using 2D fillers. / Taha-Tijerina, Jaime; Narayanan, Tharangattu N.; Gao, Guanhui; Rohde, Matthew; Tsentalovich, Dmitri A.; Pasquali, Matteo; Ajayan, Pulickel M.

In: ACS Nano, 28.02.2012, p. 1214-1220.

Research output: Contribution to journalArticle

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Taha-Tijerina J, Narayanan TN, Gao G, Rohde M, Tsentalovich DA, Pasquali M et al. Electrically insulating thermal nano-oils using 2D fillers. ACS Nano. 2012 Feb 28;1214-1220. https://doi.org/10.1021/nn203862p